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In this derivation Bohr had relied on the old idea of classical radiation theory, that the frequencies of spectral lines should agree with the frequency of the electron’s orbital motion, but he had assumed this only for the largest orbits, with large n. The light frequencies he calculated for transitions between lower states, such as n=2 → n=1, did not at all agree with the orbital frequency of the initial or final state. So Bohr’s work represented another large step away from classical physics. (en) |
